• Anti‐corrosive additives for alkaline electrolyte in Al‐air batteries: NH4VO3 and polyoxometalates 

      Atencio Estrada, Anyie Priscilla; Avilés, Juan Ramón; Bolaños, Dayatri; Urcuyo Solórzano, Roberto; Montero Villalobos, Mavis Lili; González Flores, Diego; Ocón Esteban, Pilar (2021)
      Aluminum-air batteries are a promising alternative for portable energy storage. However, one of the significant issues in this technology is the corrosion of aluminum in alkaline electrolytes. In this study, we explored ...
    • Aromatic and aliphatic thiol self-assembled monolayers on Au: Anchoring and delivering copper species 

      Urcuyo Solórzano, Roberto; Cortés Triviño, Esperanza; Rubert, Aldo A.; Benitez, G.; Montero Villalobos, Mavis Lili; Tognalli, Nicolás G.; Fainstein, Alejandro; Vela, M. E.; Salvarezza, R. C. (2011)
      The immobilization of dinuclear copper(II) acetate complexes (Cu2(CH3COO)4·2H2O) on self-assembled monolayers (SAMs) of different aliphatic and aromatic thiols with oxygen and nitrogen donors at the end group is investigated ...
    • C1 compounds shape the microbial community of an abandoned century-old oil exploration well 

      Rojas Gätjens, Diego; Fuentes Schweizer, Paola; Rojas Jiménez, Keilor Osvaldo; Pérez Pantoja, Danilo; Avendaño Vega, Roberto; Alpízar Mena, Randall; Coronado Ruiz, Carolina; Chavarría Vargas, Max (2020)
      The search for microorganisms that degrade hydrocarbons is highly relevant because it enables the bioremediation of these substances cheaply and without dangerous by-products. In this work, we studied the microbial communities ...
    • Chemical modification of graphene via hyperthermal molecular reaction 

      Dubey, Girjesh; Urcuyo Solórzano, Roberto; Abb, Sabine; Rinke, Gordon; Burghard, Marko; Rauschenbach, Stephan; Kern, Klaus (2014)
      Chemical functionalization of graphene is achieved by hyperthermal reaction with azopyridine molecular ions. The one-step, room temperature process takes place in high vacuum (10–7 mbar) using an electrospray ion beam ...
    • Electric-field control of single-molecule tautomerization 

      Mangel, Shai; Skripnik, Maxim; Polyudov, Katharina; Dette, Christian; Wollandt, Tobias; Punke, Paul; Li, Dongzhe; Urcuyo Solórzano, Roberto; Pauly, Fabian; Jung Jung, Soon; Kern, Klaus (2020)
      The electric field is an important parameter to vary in a single-molecule experiment, because it can directly affect the charge distribution around the molecule. Yet, performing such an experiment with a well-defined ...
    • Electroactive copper (II) bimetallic self-assembled multilayers on Si (100) 

      Sánchez, Alejandra; Urcuyo Solórzano, Roberto; González Flores, Diego; Montalberth Smith, Ricardo; León Rojas, Carlos; Pineda Cedeño, Leslie William; Montero Villalobos, Mavis Lili (2012)
      Silicon (100) surfaces were modified by reacting 4-aminopyridine and Si–Cl bond. These surfaces were further used for tethering copper bimetallic complexes and growing monolayers and multilayers by changing the axial ...
    • High Performance Graphene–Oxide–Metal Diode through Bias‐Induced Barrier Height Modulation 

      Urcuyo Solórzano, Roberto; Duong, Dinh Loc; Jeong, Hye Yun; Burghard, Marko; Kern, Klaus (2016)
      Graphene–oxide–metal diodes are presented whose performance is preserved even for thin oxide layers, as required for high frequency applications. The diodes, which rely upon bias-induced modulation of graphene's work ...
    • Hot carrier extraction from multilayer graphene 

      Urcuyo Solórzano, Roberto; Duong, Dinh Loc; Sailer, Patrick; Burghard, Marko; Kern, Klaus (2016)
      Hot carriers in semiconductor or metal nanostructures are relevant, for instance, to enhance the activity of oxide-supported metal catalysts or to achieve efficient photodetection using ultrathin semiconductor layers. ...
    • Oxidative dissolution of synthetic vivianites as a method for the crystallization of molecular structural motifs 

      Rojas Gatjen, Esteban; Viales Montero, Christian; Urcuyo Solórzano, Roberto; González Flores, Diego; Montero Villalobos, Mavis Lili (2021)
      Isolation of structural motifs from minerals can be used to improve the understanding of fundamental processes such as catalytic mechanisms and spectroscopic vibrations. In this study, we designed an oxidative dissolution ...
    • Perspectivas y aplicaciones reales del grafeno después de 16 años de su descubrimiento 

      Urcuyo Solórzano, Roberto; González Flores, Diego; Cordero Solano, Karla (2021)
      A 16 años del gran descubrimiento del grafeno los focos de atención vuelven a estar en este material con el reporte de su comportamiento superconductor dependiendo del apilado de sus capas. Sin embargo, su nombre durante ...
    • Production of selenium nanoparticles in Pseudomonas putida KT2440 

      Avendaño Vega, Roberto; Chaves Solano, Nefertiti; Fuentes Schweizer, Paola; Sánchez Chacón, Ethel; Jiménez, Jose Ignacio; Chavarría Vargas, Max (2016)
      Selenium (Se) is an essential element for the cell that has multiple applications in medicine and technology; microorganisms play an important role in Se transformations in the environment. Here we report the previously ...
    • Requirements for beneficial electrochemical restructuring: A model study on a cobalt oxide in selected electrolytes 

      Villalobos Porras, Javier; González Flores, Diego; Urcuyo Solórzano, Roberto; Montero Villalobos, Mavis Lili; Schuck, Götz; Beyer, Paul; Risch, Marcel (2021)
      The requirements for beneficial materials restructuring into a higher performance oxygen evolution reaction (OER) electrocatalyst are still a largely open question. Here erythrite (Co3(AsO4)2·8H2O) is used as a Co-based ...
    • Self-assembly of a catechol-based macrocycle at the liquid–solid interface: experiments and molecular dynamics simulations 

      Saiz Poseu, Javier; Martínez Otero, Alberto; Roussel, Thomas; Hui, Joseph K. H.; Montero Villalobos, Mavis Lili; Urcuyo Solórzano, Roberto; MacLachlan, Mark J.; Faraudo, Jordi; Ruiz Molina, Daniel (2012)
      This combined experimental (STM, XPS) and molecular dynamics simulation study highlights the complex and subtle interplay of solvent effects and surface interactions on the 2-D self-assembly pattern of a Schiff-base ...
    • Simple route for nano-hydroxyapatite properties expansion 

      Rojas Sánchez, Leonardo; Olmedo, Hidekel; García Piñeres, Alfonso J.; Silveira, C.; Tasic, L.; Fraga, F.; Montero Villalobos, Mavis Lili (2015-10-20)
      Simple surface modification of nano-hydroxyapatite, through acid-basic reactions, allows expanding the properties of this material. Introduction of organic groups such as hydrophobic alkyl chains, carboxylic acid, and amide ...
    • Spectroelectrochemical Experiment for Studying Water Oxidation with a Nickel Oxide Catalyst 

      González Flores, Diego; Fernández Scott, Maria Gabriela; Urcuyo Solórzano, Roberto (2020)
      Electrochemical and spectroelectrochemical techniques are very important for characterizing energy materials. In the search for new sources of renewable energy, water splitting for hydrogen production and CO2 reduction is ...
    • Temperature and elemental sulfur shape microbial communities in two extremely acidic aquatic volcanic environments 

      Rojas Gätjens, Diego; Arce Rodríguez, Alejandro; Puente Sánchez, Fernando; Avendaño Vega, Roberto; Libby Hernández, Eduardo; Mora Amador, Raúl Alberto; Rojas Jiménez, Keilor Osvaldo; Fuentes Schweizer, Paola; Pieper, Dietmar H.; Chavarría Vargas, Max (2021)
      Aquatic environments of volcanic origin provide an exceptional opportunity to study the adaptations of microbial communities to early planet life conditions such as high temperatures, high metal concentrations, and low pH. ...
    • Thin-layer black phosphorus/GaAs heterojunction pn diodes 

      Gehring, Pascal; Urcuyo Solórzano, Roberto; Duong, Dinh Loc; Burghard, Marko; Kern, Klaus (2015)
      Owing to its high carrier mobility and thickness-tunable direct band gap, black phosphorus emerges as a promising component of optoelectronic devices. Here, we evaluate the device characteristics of p-n heterojunction ...