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Monomeric Germanium(II) Amides Bearing β-Diketiminato Ligands: Synthesis, Structural Characterization, and Thermal Properties
(2014-09)Germanium(II) compounds featuring β-diketiminate-type ligands are attractive for applications as nanoparticle precursors, imaging agents, and components of electronic devices. In this work, we report the synthesis of ... -
Direct functionalization of Mn12-(methacrylate) clusters on Si(100): surface characterization and electrochemical properties
(2016-09)The reaction of H–terminated Si(100) with methacrylate–substituted manganese carboxylate clusters [Mn12O12{CH2C(CH3)COO}16(H2O)4], [Mn12–(methacrylate)] via hydrosilylation afforded Mn12–(methacrylate)−Si(100). The chemically ... -
Harnessing titanium dioxide surface toward novel functional materials
(2015)The ever-increasing worldwide energy consumption has led the society to quest for novel and functional materials that can be used in the development of solar fuels to some extent lessen the dependence on fossil fuels. In ... -
μ2-Chlorido-chlorido(μ2-4-{[2-(diethylamino)ethyl]imino}pent-2-en-2-olato)bis(tetrahydrofuran-κO)cobalt(II)lithium
(2018)The crystal structure of the title compound, [CoLi(C11H21N2O)Cl2(C4H8O)2], has monoclinic symmetry and comprises one heterometallic binuclear complex molecule in the asymmetric unit. The Co2+ cation is bonded to one oxygen ... -
Neutral organic redox pairs based on sterically hindered hydroquinone/benzoquinone derivatives for dye-sensitized solar cells
(2018-06)Substituted derivatives of hydroquinone/benzoquinone were studied as organic redox mediators in the electrolyte for dye-sensitized solar cells (DSSCs). Thus, di-tert-butylhydroquinone (DTHQ), thymohydroquinone (ThymHQ) and ... -
Synthesis and Crystal Structure of a Copper(II) Benzoate Complex Bearing a Bis-2,2′-Tetrahydrofuryl Peroxide Moiety
(2018-12)Complex [Cu2(ben)4·2THF−(η1–O2)]∞ (2) (ben=C6H5CO2− benzoate; THF=tetrahydrofuran) was isolated when a solution of Cu2(ben)4·2THF (1) in THF upon natural sunlight irradiation yields crystals suitable for single-crystal ... -
Experimental and theoretical studies of C–H⋯M interactions in palladium and platinum complexes derived from 1,2-bis-(2-hydroxymethylphenylthio)ethane
(2015-02)The molecular structures of several related cis-[j2-SS-(L)MHal2] compounds 1, 1DMSO, 2, 2H2O, 3DMSO, 4 and 5 where L = HOCH2Ph-S-CH2-CH2-S-PhCH2OH, M = Pd or Pt, and Hal = Cl or Br or I, were analyzed by single crystal ... -
Homopropargyl alcohol 1,1-diphenylbut-3-yn-1-ol
(2018)The asymmetric unit of the title compound, C16H14O, contains one molecule with a central carbon atom having a distorted tetrahedral geometry made of a propargylic fragment, a hydroxy group and two aromatic rings. ... -
Homopropargyl alcohol 5,5-diphenylpent-2-yne-1,5-diol
(2018)In the title compound, C17H16O2, the central carbon atom has a distorted tetrahedral geometry [spread of angles = 105.71 (8)–112.75 (9)°] for its bonds to a homopropargylic but-2-yn-1-ol moiety, a hydroxy group and two ... -
Composition, Chemical Fingerprinting and Antimicrobial Assessment of Costa Rican Cultivated Guavas (Psidium friedrichsthalianum (O. Berg) Nied. and Psidium guajava L.) Essential Oils from Leaves and Fruits
(2016-07-28)The essential oil of two related tree species, P. friedrichsthalianum and P. guajava, where obtained. A total of six different oil samples were recovered including leaves in dry/rainy season and fruits of both plant species. ... -
Crystal structure of 4-[(adamantan-1-yl)amino]naphthalene-1,2-dione
(2019)The title compound, C20H21NO2, an example of a stable 1,2-naphthoquinone, was determined by single-crystal X-ray diffraction analysis at 100 K. This structure illustrates steric buttressing of the adamantanyl group, forcing ... -
1,1-Diphenyl-4-(thiophen-2-yl)but-3-yn-1-ol
(2018-11)The asymmetric unit of the title homopropargyl alcohol, C20H16OS, contains two independent molecules comprising a hydroxy group, a 3-(2-thiophenyl)- propargylic moiety and two aromatic rings linked to a central carbon atom. ... -
Microwave assisted synthesis: A Mn/Ni reaction system affording Mn5Ni4, Mn2Ni2 and Mn7 complexes
(2013-11)Following our interest in microwave assisted synthesis in coordination chemistry; we report here the results of the study of a mixed metal Mn/Ni system under common bench-top conditions and using the microwave reactor. ... -
Crystal structure of (E)-2-(tert-butylamino)-4-(tertbutylimino)naphthalen-1(4H)-one
(2018)The title compound, C18H24N2O, is the first example of a naphthoquinone imine derivative isolated in the 4-imine/2-amine tautomeric form having bulky alkyl substituents at the N atoms. The molecular conformation is stabilized ... -
Dye‐sensitized Devices: Photovoltaic and Photoelectrolytic Applications
(2018-11)Dye‐sensitized approach along with stability and surface robustness in titanium dioxide (TiO2) against photocorrosion and degradation has been widely studied and applied in several important applications. This chapter ... -
Synthesis, structure and spectroscopic characterization of Ni(II), Co(II), Cu(II) and Zn(II) complexes with saccharinate and pyrazole
(2007-09)Four mononuclear mixed-ligand complexes of Co(II), Ni(II), Cu(II) and Zn(II), with saccharin (sac) and pyrazole (Hpz) were synthesized and characterized on the basis of elemental analysis, FT-IR spectroscopy, magnetic ...
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