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A new methodology for the synthesis of δ-substituted α,β-unsaturated δ-lactones
(2020)
A new protocol for the synthesis of δ-substituted-α,β-unsaturated δ-lactones was developed. Selective reaction of 1,3-dilithiopropyne with ketones, followed by addition of ethyl chloroformate formed ethyl 5-[(ethoxycarbo ...
Synthesis and Antibacterial Activity of Aromatic Homopropargyl Alcohols
(2017)
Several aromatic homopropargyl alcohols, and derivatives were prepared by
one-pot reaction of 1,3-dilithiopropyne (or its equivalent) with aldehydes and
ketones. The antibacterial activity, of alcohols ...
Propargylation of Carbonyl Compounds: An Efficient Method for the Synthesis of Homopropargyl Alcohols
(1998)
Controlled dilithiation of allene, with two equivalents of n-butytlithium, produces the propargyl dianion 5. The latter couple efficiently with carbonyl compounds to produce homopropargyl alcohols in high yields.
A New Method for the Preparation of 1-Ethynyl Ethers
(1994)
During our study of the stannylcupration of acetylenic
ethers we required [2-13C]-1 for mechanistic studies.
Existing methods for the synthesis of acetylenic ethers
involve dehydrohalogenation of 2-halo, ...
Synthesis and Biological Activity of New Antifungal Compounds: A Preliminary Study
(2018)
In the present study, we synthesized three 1,3-enynes from their corresponding aldehydes. They exhibited antifungal activity, which was evaluated against Trichophyton rubrum, the most common dermatophyte responsible for ...
A facile method for the preparation of bishomopropargylic alcohols from acyl chlorides
(2014)
Controlled dilithiation of propargyl bromide with two equivalents of n-butyllithium, in the presence of
TMEDA, produces the operational equivalent of the dianion 1,3-dilithiopropyne. The latter reacts
efficiently with ...
Síntesis de la feromona sexual de la polilla de la papa, Scrobipalpopsis Solanivora
(1988)
Se sintetizó el acetato (E) -3- dodecenilo, atrayente sexual de la polilla de la papa (Scrobipalpopsis solanivora), utilizando dos procedimientos: una ruta acetilénica y mediante la condensación de Knoevenagel.
A New Method for the Preparation of 1,5-Diynes. Synthesis of (4E,6Z,10Z)-4,6,10-Hexadecatrien-1-ol, the Pheromone Component of the Cocoa Pod Borer Moth Conopomorpha cramerella
(2004)
A new method for the synthesis of 1,5-diynes, from the reaction of 1,3-dilithiopropyne and propargyl chlorides, was developed. This new methodology was used to prepare (4E,6Z,10Z)-4,6,10-hexadecatrien-1-ol, one of the ...
Ethyl 5-[(ethoxycarbonyl)oxy]-5,5-diphenylpent-2- ynoate
(2019-11-12)
The title compound, C 22 H22 O 5, crystallizes with two molecules in the
asymmetric unit, one of which shows disorder of its ethyl acetate group over
two sets of sites in a 0.880 (2):0.120 (2) ratio. The C C distances ...
A new and efficient synthesis of (3E,8Z,11Z)-tetradeca-3,8,11-trienyl acetate, the major sex pheromone component of the tomato leafminer Tuta absoluta
(2018)
An efficient synthesis of (3E,8Z,11Z)-tetradeca-3,8,11-trienyl acetate, the major sex pheromone component of the tomato leafminer moth, Tuta absoluta, was accomplished. The synthesis started with but-3-yn-1-ol and gave an ...