| dc.creator | Solera Rojas, José Andrés | |
| dc.creator | Krause, Lennard | |
| dc.creator | Montero Villalobos, Mavis Lili | |
| dc.creator | Stalke, Dietmar | |
| dc.creator | Pineda Cedeño, Leslie William | |
| dc.date.accessioned | 2019-03-06T15:56:43Z | |
| dc.date.available | 2019-03-06T15:56:43Z | |
| dc.date.issued | 2018-12 | |
| dc.identifier.citation | https://link.springer.com/article/10.1007%2Fs10870-018-0721-7 | |
| dc.identifier.issn | 1572-8854 | |
| dc.identifier.uri | https://hdl.handle.net/10669/76671 | |
| dc.description.abstract | Complex [Cu2(ben)4·2THF−(η1–O2)]∞ (2) (ben=C6H5CO2− benzoate; THF=tetrahydrofuran) was isolated when a solution of Cu2(ben)4·2THF (1) in THF upon natural sunlight irradiation yields crystals suitable for single-crystal X-ray diffraction analysis. 2, crystallized in the C2/c monoclinic space group, Z=8, V=3394.2 (4) Å3, and the unit cell parameters a=9.7935(7) Å, b=19.0055 (13) Å, c=18.2997 (13) Å, α=90°, β=94.7996 (11)º and γ=90°. This is the first example of a polymeric copper(II) carboxylate compound stabilizing a peroxo group via its apical ligand (THF molecule). Additionally, 2 was also characterized by elemental analysis, Fourier-transformed infrared spectroscopy (FTIR) and Raman spectroscopy | es_ES |
| dc.description.sponsorship | Universidad de Costa Rica/[804-B7-279]/UCR/Costa Rica | es_ES |
| dc.description.sponsorship | Universidad de Costa Rica/[804-B0-650]/UCR/Costa Rica | es_ES |
| dc.language.iso | en_US | es_ES |
| dc.relation.ispartof | | |
| dc.source | Journal of Chemical Crystallography, vol. 48(4), pp. 138–144 | es_ES |
| dc.subject | Copper(II) benzoate | es_ES |
| dc.subject | Tetrahydrofuryl peroxide | es_ES |
| dc.subject | Coordination complex | es_ES |
| dc.subject | Sunlight-promoted reaction | es_ES |
| dc.subject | Peroxide formation | es_ES |
| dc.subject | 540 Química | es_ES |
| dc.title | Synthesis and Crystal Structure of a Copper(II) Benzoate Complex Bearing a Bis-2,2′-Tetrahydrofuryl Peroxide Moiety | es_ES |
| dc.type | artículo original | |
| dc.date.updated | 2018-12-13T00:36:49Z | |
| dc.identifier.doi | 10.1007/s10870-018-0721-7 | |
| dc.description.procedence | UCR::Vicerrectoría de Docencia::Ciencias Básicas::Facultad de Ciencias::Escuela de Química | es_ES |
| dc.description.procedence | UCR::Vicerrectoría de Investigación::Unidades de Investigación::Ciencias Básicas::Centro de Investigación en Electroquímica y Energía Química (CELEQ) | es_ES |
| dc.identifier.codproyecto | 804-B7-279 | |
| dc.identifier.codproyecto | 804-B0-650 | |
