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Synthesis of Iodinated Naphthoquinones Using Morpholine-Iodine Complex
(Synthetic Communications Vol. 34, No. 18, pp. 3389–3397, 2004, 2004)
The efficient synthesis of 2‐hydroxy‐3‐iodo‐1,4‐naphthoquinone (3), 2‐amino‐3‐iodo‐1,4‐naphthoquinone (4), and 2‐iodo‐1,4‐naphthoquinone (5) have been developed using the parent naphthoquinone in combination with the ...
Experimental and theoretical studies of C–H⋯M interactions in palladium and platinum complexes derived from 1,2-bis-(2-hydroxymethylphenylthio)ethane
(2015-02)
The molecular structures of several related cis-[j2-SS-(L)MHal2] compounds 1, 1DMSO, 2, 2H2O,
3DMSO, 4 and 5 where L = HOCH2Ph-S-CH2-CH2-S-PhCH2OH, M = Pd or Pt, and Hal = Cl or Br or I, were analyzed by single crystal ...
Essential oils of Baccharis trinervis (Asteraceae) from Costa Rica
Constituyentes de los aceites esenciales de Baccharis trinervis (Asteraceae) de Costa Rica
(2017)
Baccharis is an Asteraceae genus of flowering plants, which has about 340 to 400 species, ranging from the Southern United States to the Southern extreme of Argentina and Chile through Central America and the Caribbean ...
Evaluation of a recent product to remove lipids and other matrix co-extractives in the analysis of pesticide residues and environmental contaminants in foods
(2016-06-03)
This study demonstrates the application of a novel lipid removal product to the residue analysis of 65 pesticides and 52 environmental contaminants in kale, pork, salmon, and avocado by fast, low pressure gas chromatography ...
Granular Activated Carbon Treatment May Result in Higher Predicted Genotoxicity in the Presence of Bromide
(2016-07-28)
Certain unregulated disinfection byproducts (DBPs) are more of a health concern than regulated DBPs. Brominated species are typically more cytotoxic and genotoxic than their chlorinated analogs. The impact of granular ...
Removal of N-nitrosodimethylamine precursors with powdered activated carbon adsorption
(2016-01-01)
The main objective of this study was to examine the roles of powdered activated carbon (PAC) characteristics (i.e., surface chemistry, pore size distribution, and surface area) in the removal of N-nitrosodimethylamine ...
Design of an optimized biomixture for the degradation of carbofuran based on pesticide removal and toxicity reduction of the matrix
(2015-12)
Pesticide biopurification systems contain a biologically active matrix (biomixture) responsible for the accelerated elimination of pesticides in wastewaters derived from pest control in crop fields. Biomixtures have been ...
Synthesis of 2-hydroxy-3-substituted naphthoquinones using the Heck reaction
(2007-06)
An efficient Heck coupling of 2-hydroxy-3-iodo-naphthoquinone with a series of electron-deficient alkenes in aqueous solution has been accomplished. The method is characterized by simple conditions and facile work-up to ...
A Metabolic Widget Adjusts the Phosphoenolpyruvate-Dependent Fructose Influx in Pseudomonas putida
(2016)
Fructose uptake in the soil bacterium Pseudomonas putida occurs through a canonical phosphoenolpyruvate (PEP)-dependent sugar transport system (PTSFru). The logic of the genetic circuit that rules its functioning is puzzling: ...
The Bacterial Product Violacein Exerts an Immunostimulatory Effect Via TLR8
(2019)
Violacein, an indole-derived, purple-colored natural pigment isolated from Chromobacterium violaceum has shown multiple biological activities. In this work, we studied the effect of violacein in different immune cell lines, ...