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Synthesis and Crystal Structure of a Copper(II) Benzoate Complex Bearing a Bis-2,2′-Tetrahydrofuryl Peroxide Moiety

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dc.creatorSolera Rojas, José Andrés
dc.creatorKrause, Lennard
dc.creatorMontero Villalobos, Mavis Lili
dc.creatorStalke, Dietmar
dc.creatorPineda Cedeño, Leslie William
dc.date.accessioned2019-03-06T15:56:43Z
dc.date.available2019-03-06T15:56:43Z
dc.date.issued2018-12
dc.date.updated2018-12-13T00:36:49Z
dc.description.abstractComplex [Cu2(ben)4·2THF−(η1–O2)]∞ (2) (ben=C6H5CO2− benzoate; THF=tetrahydrofuran) was isolated when a solution of Cu2(ben)4·2THF (1) in THF upon natural sunlight irradiation yields crystals suitable for single-crystal X-ray diffraction analysis. 2, crystallized in the C2/c monoclinic space group, Z=8, V=3394.2 (4) Å3, and the unit cell parameters a=9.7935(7) Å, b=19.0055 (13) Å, c=18.2997 (13) Å, α=90°, β=94.7996 (11)º and γ=90°. This is the first example of a polymeric copper(II) carboxylate compound stabilizing a peroxo group via its apical ligand (THF molecule). Additionally, 2 was also characterized by elemental analysis, Fourier-transformed infrared spectroscopy (FTIR) and Raman spectroscopyes_ES
dc.description.procedenceUCR::Vicerrectoría de Docencia::Ciencias Básicas::Facultad de Ciencias::Escuela de Químicaes_ES
dc.description.procedenceUCR::Vicerrectoría de Investigación::Unidades de Investigación::Ciencias Básicas::Centro de Investigación en Electroquímica y Energía Química (CELEQ)es_ES
dc.description.sponsorshipUniversidad de Costa Rica/[804-B7-279]/UCR/Costa Ricaes_ES
dc.description.sponsorshipUniversidad de Costa Rica/[804-B0-650]/UCR/Costa Ricaes_ES
dc.identifier.citationhttps://link.springer.com/article/10.1007%2Fs10870-018-0721-7
dc.identifier.codproyecto804-B7-279
dc.identifier.codproyecto804-B0-650
dc.identifier.doi10.1007/s10870-018-0721-7
dc.identifier.issn1572-8854
dc.identifier.urihttps://hdl.handle.net/10669/76671
dc.language.isoen_USes_ES
dc.relation.ispartof
dc.rightsacceso embargado
dc.sourceJournal of Chemical Crystallography, vol. 48(4), pp. 138–144es_ES
dc.subjectCopper(II) benzoatees_ES
dc.subjectTetrahydrofuryl peroxidees_ES
dc.subjectCoordination complexes_ES
dc.subjectSunlight-promoted reactiones_ES
dc.subjectPeroxide formationes_ES
dc.subject540 Químicaes_ES
dc.titleSynthesis and Crystal Structure of a Copper(II) Benzoate Complex Bearing a Bis-2,2′-Tetrahydrofuryl Peroxide Moietyes_ES
dc.typeartículo original

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