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Synthesis of 2-hydroxy-3-substituted naphthoquinones using the Heck reaction
(2007-06)
An efficient Heck coupling of 2-hydroxy-3-iodo-naphthoquinone with a series of electron-deficient alkenes in aqueous solution has been accomplished. The method is characterized by simple conditions and facile work-up to ...
A new methodology for the synthesis of δ-substituted α,β-unsaturated δ-lactones
(2020)
A new protocol for the synthesis of δ-substituted-α,β-unsaturated δ-lactones was developed. Selective reaction of 1,3-dilithiopropyne with ketones, followed by addition of ethyl chloroformate formed ethyl 5-[(ethoxycarbo ...
Synthesis and Antibacterial Activity of Aromatic Homopropargyl Alcohols
(2017)
Several aromatic homopropargyl alcohols, and derivatives were prepared by
one-pot reaction of 1,3-dilithiopropyne (or its equivalent) with aldehydes and
ketones. The antibacterial activity, of alcohols ...
Condensación de Cetonas Alifáticas con la Fenantrenoquinona en Hidróxido de Amonio
(1971)
A study on the synthesis and structure of the products of condensation of phenanthrenequinone with acetone and methyl-ethyl-ketone in presence of ammonia was
made. The structures were established by spectroscopic methods. ...
Propargylation of Carbonyl Compounds: An Efficient Method for the Synthesis of Homopropargyl Alcohols
(1998)
Controlled dilithiation of allene, with two equivalents of n-butytlithium, produces the propargyl dianion 5. The latter couple efficiently with carbonyl compounds to produce homopropargyl alcohols in high yields.
β-Carboline monoterpenoid glucosides from Palicourea adusta
(1999)
Lyaloside, a monoterpenoid glucoindole alkaloid, was isolated from the leaves of Palicourea adusta together with a mixture of its hydroxycinnamic acid derivatives, (E)-O-(6′)-cinnamoyl-4″-hydroxy-3″-methoxy-lyaloside and ...
A New Method for the Preparation of 1-Ethynyl Ethers
(1994)
During our study of the stannylcupration of acetylenic
ethers we required [2-13C]-1 for mechanistic studies.
Existing methods for the synthesis of acetylenic ethers
involve dehydrohalogenation of 2-halo, ...
Bile salts and derivatives: Rigid unconventional amphiphiles as dispersants, carriers and superstructure building blocks
(2015)
Steroidal surfactants like bile salts have a rigid amphiphilic structure significantly different from the typical head–tail one. As a result, these molecules show peculiar features in their self-assembly behavior and ...
Photoreactivity of Oil and Alcoholic Diterpenic Varnishes: Key Role of the Polymerization Process
(2020)
he conservation of artworks is a key issue in cultural heritage. The alterations of the varnish could be linked mainly to the photopolymerization of the natural resin. The photodegrada- tion of sandarac and rosin under ...
Use of a theoretical prediction method and quantum chemical calculations for the design, synthesis and experimental evaluation of three green corrosion inhibitors for mild steel
(2020)
Three phenylmethanimine derivatives (Schiff bases) were designed after a theoretical prediction of their corrosion inhibition efficiencies and a corroboration through the use of quantum chemical calculations. The molecules ...