Logo Kérwá
 

1,3-Bis{[(2,6-di­methyl­phen­yl)sulfan­yl]meth­yl}benzene

Loading...
Thumbnail Image

Date

Authors

Garita Salazar, Bruno
Pineda Cedeño, Leslie William

Journal Title

Journal ISSN

Volume Title

Publisher

Abstract

The structure of the title compound, C24H26S2, an example of a pincer ligand with an SCS-chelation motif, illustrates the steric effects of the methyl groups in the thio­phenyl rings at the 2- and 6-positions, forcing a dissimilar spatial orientation of the thio­phenyl rings relative to the central aryl group [dihedral angles = 33.58 (7) and 40.49 (7)°]. In the crystal, weak S⋯S contacts [3.4009 (7) Å] link the mol­ecules into inversion dimers.

Description

Keywords

Ligandos pinza, Azufre, Efecto quelato, Estabilización cinética, Crystal structure, Chelating ligand, SCS pincer ligands, Kinetic stabilization, Sulfur atom

Citation

https://iucrdata.iucr.org/x/issues/2019/05/00/hb4295/index.html

Collections

Endorsement

Review

Supplemented By

Referenced By