1,3-Bis{[(2,6-dimethylphenyl)sulfanyl]methyl}benzene
Fecha
2019
Tipo
artículo original
Autores
Garita Salazar, Bruno
Pineda Cedeño, Leslie William
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Resumen
The structure of the title compound, C24H26S2, an example of a pincer ligand with an SCS-chelation motif, illustrates the steric effects of the methyl groups in the thiophenyl rings at the 2- and 6-positions, forcing a dissimilar spatial orientation of the thiophenyl rings relative to the central aryl group [dihedral angles = 33.58 (7) and 40.49 (7)°]. In the crystal, weak S⋯S contacts [3.4009 (7) Å] link the molecules into inversion dimers.
Descripción
Palabras clave
Ligandos pinza, Azufre, Efecto quelato, Estabilización cinética, Crystal structure, Chelating ligand, SCS pincer ligands, Kinetic stabilization, Sulfur atom