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1,3-Bis{[(2,6-di­methyl­phen­yl)sulfan­yl]meth­yl}benzene

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dc.creatorGarita Salazar, Bruno
dc.creatorPineda Cedeño, Leslie William
dc.date.accessioned2020-08-06T19:38:16Z
dc.date.available2020-08-06T19:38:16Z
dc.date.issued2019
dc.description.abstractThe structure of the title compound, C24H26S2, an example of a pincer ligand with an SCS-chelation motif, illustrates the steric effects of the methyl groups in the thio­phenyl rings at the 2- and 6-positions, forcing a dissimilar spatial orientation of the thio­phenyl rings relative to the central aryl group [dihedral angles = 33.58 (7) and 40.49 (7)°]. In the crystal, weak S⋯S contacts [3.4009 (7) Å] link the mol­ecules into inversion dimers.es_ES
dc.description.procedenceUCR::Vicerrectoría de Docencia::Ciencias Básicas::Facultad de Ciencias::Escuela de Químicaes_ES
dc.description.procedenceUCR::Vicerrectoría de Investigación::Unidades de Investigación::Ciencias Básicas::Centro de Investigación en Electroquímica y Energía Química (CELEQ)es_ES
dc.description.sponsorshipUniversidad de Costa Rica/[804-B7-274]/UCR/Costa Ricaes_ES
dc.identifier.citationhttps://iucrdata.iucr.org/x/issues/2019/05/00/hb4295/index.html
dc.identifier.codproyecto804-B7-274
dc.identifier.doi10.1107/S2414314619006771
dc.identifier.issn2414-3146
dc.identifier.urihttps://hdl.handle.net/10669/81417
dc.language.isoen_USes_ES
dc.rightsacceso abierto
dc.sourceIUCrData, vol.4(5), 1-3es_ES
dc.subjectLigandos pinzaes_ES
dc.subjectAzufrees_ES
dc.subjectEfecto quelatoes_ES
dc.subjectEstabilización cinéticaes_ES
dc.subjectCrystal structurees_ES
dc.subjectChelating ligandes_ES
dc.subjectSCS pincer ligandses_ES
dc.subjectKinetic stabilizationes_ES
dc.subjectSulfur atomes_ES
dc.title1,3-Bis{[(2,6-di­methyl­phen­yl)sulfan­yl]meth­yl}benzenees_ES
dc.typeartículo original

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